A kinetic investigation of ethyl formate elimination from the polymeric adduct [MgCl2(HCOOC2H5)2]n (V. Di Noto, G. Bandoli, S. Bresadola, R. Zannetti and M. Viviani, submitted to Z. Kristallogr) has been carried out under a rigorously inert atmosphere at reduced pressure by means of thermogravimetric measurements. The elimination appears to occur in two steps which agree well with rate laws of the first and second order of reaction, respectively. The activation energies of these elimination reactions have been also determined and a reaction mechanism is proposed.

A kinetic investigation of ethyl formate elimination from the [MgCl2(HCOOC2H5)2]n adduct using thermoanalytical data

DI NOTO, VITO;
1991

Abstract

A kinetic investigation of ethyl formate elimination from the polymeric adduct [MgCl2(HCOOC2H5)2]n (V. Di Noto, G. Bandoli, S. Bresadola, R. Zannetti and M. Viviani, submitted to Z. Kristallogr) has been carried out under a rigorously inert atmosphere at reduced pressure by means of thermogravimetric measurements. The elimination appears to occur in two steps which agree well with rate laws of the first and second order of reaction, respectively. The activation energies of these elimination reactions have been also determined and a reaction mechanism is proposed.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/123870
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