Here we present the electrochemical and optical properties of syn and anti [CpFe-(mu-eta5:eta5-as-indacene-diide)-RhL2]+ (L2 = cyclooctadiene, norborna- diene, L = CO) mixed valence ions (Fig. 2) generated by chemical and electrochemical oxidation of the corresponding neutral complexes. The huge enhancement of the reactivity in the substitution of COD and NBD with carbon monoxide induced by electron transfer will be discussed.
Redox-triggered molecular switches: electronic communication in heterobimetallic indacenyl mixed valence complexes
SANTI, SAVERIO;CECCON, ALBERTO;GAMBARO, ALESSANDRO;TISO, MAURO;
2002
Abstract
Here we present the electrochemical and optical properties of syn and anti [CpFe-(mu-eta5:eta5-as-indacene-diide)-RhL2]+ (L2 = cyclooctadiene, norborna- diene, L = CO) mixed valence ions (Fig. 2) generated by chemical and electrochemical oxidation of the corresponding neutral complexes. The huge enhancement of the reactivity in the substitution of COD and NBD with carbon monoxide induced by electron transfer will be discussed.
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