Silica films co-implanted with Er and Au ions show an enhancement of rare earth photoluminescence after gold introduction in the matrix. Er excitation originates in a broad spectral region, from the red to the near ultraviolet. We have investigated the influence of gold aggregation on the optical properties of co-doped samples by varying the temperature of post-Au implantation annealing in the 400-900 degrees C range. Optical measurements and extended x-ray absorption analysis support the hypothesis of an energy transfer process mediated by sub-nanometric Au aggregates with metallic character that are optically activated mostly through electron interband transitions between d and sp-conduction levels.

Sub-nanometric metallic Au clusters as efficient Er3+ sensitizers in silica

TRAVE, ENRICO;MATTEI, GIOVANNI;MAZZOLDI, PAOLO;PELLEGRINI, GIOVANNI;SCIAN, CARLO;MAURIZIO, CHIARA;
2006

Abstract

Silica films co-implanted with Er and Au ions show an enhancement of rare earth photoluminescence after gold introduction in the matrix. Er excitation originates in a broad spectral region, from the red to the near ultraviolet. We have investigated the influence of gold aggregation on the optical properties of co-doped samples by varying the temperature of post-Au implantation annealing in the 400-900 degrees C range. Optical measurements and extended x-ray absorption analysis support the hypothesis of an energy transfer process mediated by sub-nanometric Au aggregates with metallic character that are optically activated mostly through electron interband transitions between d and sp-conduction levels.
2006
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/144259
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