A mean-field model for the analysis of electrostatic interactions in liquid crystal phases is proposed. The model is based on a realistic description of the probe molecule and a continuum approximation for its environment. Electrostatic interactions, treated with the reaction field model, are superimposed to short-range interactions, which are accounted for by a shape method. The model is used to predict orientational order parameters of some representative solutes, characterized by different shapes and charge distributions, dissolved in nematics with different dielectric permittivities.
Effects of electrostatic interactions on orientational order of solutes in liquid crystals
DI MATTEO, ANDREA;FERRARINI, ALBERTA;MORO, GIORGIO
2000
Abstract
A mean-field model for the analysis of electrostatic interactions in liquid crystal phases is proposed. The model is based on a realistic description of the probe molecule and a continuum approximation for its environment. Electrostatic interactions, treated with the reaction field model, are superimposed to short-range interactions, which are accounted for by a shape method. The model is used to predict orientational order parameters of some representative solutes, characterized by different shapes and charge distributions, dissolved in nematics with different dielectric permittivities.File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
