The anomalously low basicity of two sterically hindered ketones (Bu(2)(t)CO and PhCOBu(t)) stems from steric hindrance to the solvation of their protonated forms.
STERIC EFFECTS ON THE SOLVATION OF PROTONATED DI-TERT-BUTYL KETONE AND PHENYL TERT-BUTYL KETONE
BAGNO, ALESSANDRO;SCORRANO, GIANFRANCO
1995
Abstract
The anomalously low basicity of two sterically hindered ketones (Bu(2)(t)CO and PhCOBu(t)) stems from steric hindrance to the solvation of their protonated forms.File in questo prodotto:
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