A new type of ligating behaviour of the phosphirene ring system PPhCPh=CPh is described, in which novel dimeric platinum(II) chlorophosphane complexes result from phosphirene ring opening and a Pt-Cl bond-insertion reaction.

Novel Ring-opening and Halogen Transfer From Platinum(II) To Phosphorus In the Reaction of [PtCl2(CNR)2] (R = Bu-t, p-MeOC6H4) With the Phosphirene Ring PPhCPh=CPh - Crystal and Molecular-structure of the Dimeric Chlorophosphane Complex [PtCl(PClPhCPh=CPh)(CNBu-t)]2

MICHELIN, RINO;
1993

Abstract

A new type of ligating behaviour of the phosphirene ring system PPhCPh=CPh is described, in which novel dimeric platinum(II) chlorophosphane complexes result from phosphirene ring opening and a Pt-Cl bond-insertion reaction.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/2496091
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