The technique of DSC (Differential Scanning Calorimetry-Differential scanning calorimetry) was used to isolate the parameters of diffusion of molecules during the polymerization of methyl methacrylate in bulk and solution. Dissemination has an impact on the dynamics of the polymerization at high conversion as well as product properties. We present here an analysis of the effect of monomer concentration on the kinetic parameters and parameters related to diffusion. The presence of a solvent has a strong influence on the kinetics of polymerization.

Analysis of diffusion phenomena in free radical polymerization by microcalorimetry

MASCHIO, GIUSEPPE
1998

Abstract

The technique of DSC (Differential Scanning Calorimetry-Differential scanning calorimetry) was used to isolate the parameters of diffusion of molecules during the polymerization of methyl methacrylate in bulk and solution. Dissemination has an impact on the dynamics of the polymerization at high conversion as well as product properties. We present here an analysis of the effect of monomer concentration on the kinetic parameters and parameters related to diffusion. The presence of a solvent has a strong influence on the kinetics of polymerization.
1998
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/2522484
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