The photochemistry of Mn2(CO)10 in the presence of phosphine ligands has been investigated. Steric hindrance by the phosphine molecules influences the products of the photolysis reaction. With ethyldiphenylphosphine disubstituted symmetrical species are obtained. © 1983.
Steric effects of phosphine ligands on the photochemistry of Mn2(CO)10
BERTANI, ROBERTA
1983
Abstract
The photochemistry of Mn2(CO)10 in the presence of phosphine ligands has been investigated. Steric hindrance by the phosphine molecules influences the products of the photolysis reaction. With ethyldiphenylphosphine disubstituted symmetrical species are obtained. © 1983.
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