The title complex was prepared by reacting Pd(AcO)(2) first with dppp and then with TsOH . H2O in MeOH at r.t. It is highly active in CO-C2H4 copolymerization in MeOH. It has been characterized by IR and H-1 and P-31 NMR spectroscopies. The X-ray structure consists of a packing of monomeric palladium cations and tosylate anions in the ratio 1:1. The palladium atom is in rather distorted square coordination.
SYNTHESIS, CHARACTERIZATION AND X-RAY STRUCTURE OF [PD(DPPP)(H2O)(TSO)] [TSO] (DPPP=1,3-BIS(DIPHENYLPHOSPHINO)PROPANE - TSO=P-CH3C6H4SO3), A CATALYTIC SPECIES IN CO-C2H4 COPOLYMERIZATION
BERTANI, ROBERTA;
1995
Abstract
The title complex was prepared by reacting Pd(AcO)(2) first with dppp and then with TsOH . H2O in MeOH at r.t. It is highly active in CO-C2H4 copolymerization in MeOH. It has been characterized by IR and H-1 and P-31 NMR spectroscopies. The X-ray structure consists of a packing of monomeric palladium cations and tosylate anions in the ratio 1:1. The palladium atom is in rather distorted square coordination.File in questo prodotto:
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