monochloroacetic acid were detd. in 1.00 M NaClO4 at 25 °C. Comparison is given with literature data for the Th(IV)-acetate system. The thermodn. values for the two systems indicate a lower stability for the Th-monochloroacetate complexes as compared to the Th-acetate complexes. The lower ligand basicity results in both a weaker metal-ligand interaction and a more extensive hydration of the complexes formed
Thermodynamic Properties of Actinide Complexes. Part VI. Thorium(IV) - Monochloroacetate System.
DI BERNARDO, PLINIO;
1978
Abstract
monochloroacetic acid were detd. in 1.00 M NaClO4 at 25 °C. Comparison is given with literature data for the Th(IV)-acetate system. The thermodn. values for the two systems indicate a lower stability for the Th-monochloroacetate complexes as compared to the Th-acetate complexes. The lower ligand basicity results in both a weaker metal-ligand interaction and a more extensive hydration of the complexes formedFile in questo prodotto:
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