The formation of vanadyl(IV) complexes with acetates were studied by potentiometric titrn. methods; the stepwise formation consts. of mononuclear complexes, [VO(CH3COO)]+ and [VO(CH3COO)2], were calcd. to be 72.2 and 12.6 M-1, resp., in 1 M aq. perchlorate at 25 °C. A comparison was made with the literature values for the corresponding neptunyl(IV) complexes.
Vanadyl(IV) - Acetate Complexes in Aqueous Solution.
DI BERNARDO, PLINIO
1981
Abstract
The formation of vanadyl(IV) complexes with acetates were studied by potentiometric titrn. methods; the stepwise formation consts. of mononuclear complexes, [VO(CH3COO)]+ and [VO(CH3COO)2], were calcd. to be 72.2 and 12.6 M-1, resp., in 1 M aq. perchlorate at 25 °C. A comparison was made with the literature values for the corresponding neptunyl(IV) complexes.File in questo prodotto:
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