The complex formation of vanadyl(IV) with monochloroacetate, β-chloropropionate and glycolate ions was studied by potentiometric [H+] measurements in 1 M NaClO4 soln. at 25 °C. The VO2+ ion forms mononuclear successive complexes with a coordination no. > 2. The relationship between the stability of the vanadyl complexes and the ligand basicity is discussed.
Vanadyl(IV) - Monocarboxylate Complexes in Aqueous Solution.
DI BERNARDO, PLINIO
1981
Abstract
The complex formation of vanadyl(IV) with monochloroacetate, β-chloropropionate and glycolate ions was studied by potentiometric [H+] measurements in 1 M NaClO4 soln. at 25 °C. The VO2+ ion forms mononuclear successive complexes with a coordination no. > 2. The relationship between the stability of the vanadyl complexes and the ligand basicity is discussed.File in questo prodotto:
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