The rhenium(V) imido-complexes [Re(NR)Cl3(PPh3)2] have been obtained by heating the rhenium(V) derivative [ReOCl3(PPh3)2] with RNHCHNR R = Ph (1a), p-MeC6H4 (1b), p-ClC6H4 (1c) andp-FC6H4 (1d) in THF under reflux. [Re(NR)Cl3(PPh3)2] (R =p-MeQ6H4) has also been obtained by heating the rhenium(III)-triazenido complex [ReCl2(RN [(-)\ddot]−N [(-)\ddot]−NR)(PPh3)2] in CCl4 under reflux.

Formamidines and Triazenes as Precursors for the Preparation of Rhenium Imido-Complexes.

DI BERNARDO, PLINIO
1985

Abstract

The rhenium(V) imido-complexes [Re(NR)Cl3(PPh3)2] have been obtained by heating the rhenium(V) derivative [ReOCl3(PPh3)2] with RNHCHNR R = Ph (1a), p-MeC6H4 (1b), p-ClC6H4 (1c) andp-FC6H4 (1d) in THF under reflux. [Re(NR)Cl3(PPh3)2] (R =p-MeQ6H4) has also been obtained by heating the rhenium(III)-triazenido complex [ReCl2(RN [(-)\ddot]−N [(-)\ddot]−NR)(PPh3)2] in CCl4 under reflux.
1985
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/115504
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