Enthalpic and entropic contributions to the formation of actinide complexes with different ligands have been evaluated. The literature data are in agreement with an entropic stabilization of the complexes, while the enthalpy term, except in few cases, opposes the complex formation. Both ΔS and ΔH values decrease with increasing coordination of ligands. Informations have been gained on the nature of reactions and bonding.

Proprietà termodinamiche di complessi di ioni attinoidi in soluzione acquosa.

DI BERNARDO, PLINIO;
1974

Abstract

Enthalpic and entropic contributions to the formation of actinide complexes with different ligands have been evaluated. The literature data are in agreement with an entropic stabilization of the complexes, while the enthalpy term, except in few cases, opposes the complex formation. Both ΔS and ΔH values decrease with increasing coordination of ligands. Informations have been gained on the nature of reactions and bonding.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/116157
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