Calculations are presented of the energetics of an impurity (atom or ion) interacting with a fluid. Two possible configurations are considered: a surface state and a solvated state. For two distinct model problems which we consider (any classical fluid and superfluid helium) we find a common behaviour: the value of a dimensionless parameter lambda determines the relative stability of the surface and solvated states. For lambda greater (less) than 1.9, the sovated (surface) stare is favored, A more realistic estimate for a classical fluid is lambda similar to 1. Predictions are made of a universal solvation behaviour derived from the law of corresponding states. Results are presented for the solvated fraction as a function of cluster radius and temperature. Quantum corrections and the kinetics of solvation are discussed briefly.
Physics of solvation
ANCILOTTO, FRANCESCO;
1995
Abstract
Calculations are presented of the energetics of an impurity (atom or ion) interacting with a fluid. Two possible configurations are considered: a surface state and a solvated state. For two distinct model problems which we consider (any classical fluid and superfluid helium) we find a common behaviour: the value of a dimensionless parameter lambda determines the relative stability of the surface and solvated states. For lambda greater (less) than 1.9, the sovated (surface) stare is favored, A more realistic estimate for a classical fluid is lambda similar to 1. Predictions are made of a universal solvation behaviour derived from the law of corresponding states. Results are presented for the solvated fraction as a function of cluster radius and temperature. Quantum corrections and the kinetics of solvation are discussed briefly.Pubblicazioni consigliate
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