Ti2Cl8O4C10H20, Mr = 583.69, triclinic, PI, a = 9.372(2) Angstrom, b = 8.979(2) Angstrom, c = 7.812(2) Angstrom, alpha = 63.5(2)°, beta = 76.2(2)°, gamma = 77.5(2)°, V = 567(1) Angstrom3, Dx=1.71 g/cm3, lambda(MoKa) = 0.71069 Angstrom, mu = 15.53 cm-1, F(000) = 292, T = 294 K, m.p. 85 - 90° C, final R = 0.036 for 2248 observed reflections with F> 7sigma(F). The structure is built up of dimeric molecules and the unit cell contains only one dimeric unit. The dimerization occurs through two chlorine bridges between thè titanium atoms which are coordinated by five chlorine atoms and one carbonyl oxygen atom of the ester moiety in an almost perfect octahedral environment.

Synthesis and crystal structure of the titanium tetrachloride-ethyl propionate adduct

DI NOTO, VITO;
1991

Abstract

Ti2Cl8O4C10H20, Mr = 583.69, triclinic, PI, a = 9.372(2) Angstrom, b = 8.979(2) Angstrom, c = 7.812(2) Angstrom, alpha = 63.5(2)°, beta = 76.2(2)°, gamma = 77.5(2)°, V = 567(1) Angstrom3, Dx=1.71 g/cm3, lambda(MoKa) = 0.71069 Angstrom, mu = 15.53 cm-1, F(000) = 292, T = 294 K, m.p. 85 - 90° C, final R = 0.036 for 2248 observed reflections with F> 7sigma(F). The structure is built up of dimeric molecules and the unit cell contains only one dimeric unit. The dimerization occurs through two chlorine bridges between thè titanium atoms which are coordinated by five chlorine atoms and one carbonyl oxygen atom of the ester moiety in an almost perfect octahedral environment.
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

Caricamento pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11577/123869
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 6
  • ???jsp.display-item.citation.isi??? 4
social impact