Novel insoluble isonitrile-bearing polymeric supports display versatile and strong ligating ability towards a variety of transition metal centres. The combination of controlled stoichiometry, elemental analysis, and IR spectroscopy gives reliable information on the nature of the molecular coordination compounds formed. The PdCl2-containing polymers are effective catalysts for the hydrogenation of benzaldehyde and phenylacetylene under mild conditions.
ISONITRILE-FUNCTIONALIZED POLYMER SUPPORTS AS VERSATILE LIGANDS TOWARDS METAL CENTERS
CORAIN, BENEDETTO;BASATO, MARINO;ZECCA, MARCO;
1987
Abstract
Novel insoluble isonitrile-bearing polymeric supports display versatile and strong ligating ability towards a variety of transition metal centres. The combination of controlled stoichiometry, elemental analysis, and IR spectroscopy gives reliable information on the nature of the molecular coordination compounds formed. The PdCl2-containing polymers are effective catalysts for the hydrogenation of benzaldehyde and phenylacetylene under mild conditions.
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