The reaction of the oxocumulene ylide ketenylidenetriphenylphosphorane, Ph,PC=C=O (1), with an excess of water in THF yields a white microcrystalline solid, methyltriphenylphosphonium hydrogencarbonate, which contains one molecule of crystallization water, [Ph3MeP](CO3HH2O)-H-. (2). Compound 2 was characterized by IR, multinuclear NMR and ESI mass spectra. The chemical constitution was confirmed by X-ray crystal analysis. On heating, compound 2 decomposes giving CO2, H2O, C6H6 and Ph(2)MepO.

TI: Reaction of ketenylidenetriphenylphosphorane, Ph3PC=C=O, with water: formation of methyltriphenylphosphonium hydrogencarbonate

BERTANI, ROBERTA;PANDOLFO, LUCIANO
2002

Abstract

The reaction of the oxocumulene ylide ketenylidenetriphenylphosphorane, Ph,PC=C=O (1), with an excess of water in THF yields a white microcrystalline solid, methyltriphenylphosphonium hydrogencarbonate, which contains one molecule of crystallization water, [Ph3MeP](CO3HH2O)-H-. (2). Compound 2 was characterized by IR, multinuclear NMR and ESI mass spectra. The chemical constitution was confirmed by X-ray crystal analysis. On heating, compound 2 decomposes giving CO2, H2O, C6H6 and Ph(2)MepO.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/1334990
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