A multidimensional diffusional approach is proposed to describe rotational diffusion or conformational transition in molecular systems in the presence of coupling with polar solvent coordinates. The model is applied to interpret dielectric friction effects and Twisted Intramolecular Charge Transfer (TICT) kinetics. Full numerical solutions are compared with those obtained by approximate procedures.
Multivariate diffusion models of dielectric friction and TICT transitions (Reprinted from Mol. Phys., vol 68, pg 1131-1141, 1989)
G. J. MORO;POLIMENO, ANTONINO
2003
Abstract
A multidimensional diffusional approach is proposed to describe rotational diffusion or conformational transition in molecular systems in the presence of coupling with polar solvent coordinates. The model is applied to interpret dielectric friction effects and Twisted Intramolecular Charge Transfer (TICT) kinetics. Full numerical solutions are compared with those obtained by approximate procedures.File in questo prodotto:
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