Copper(II) salts react with the bidentate hybrid ligands 1-thiophenyl-2-diphenylphosphinoethane (PSPh) and 1-thioethyl-2-diphehylphosphinoethane (PSEt) to yield copper(I) and/of copper(II) complexes of composition [Cu(PSR)2]Y andCu- (OPSR)2] Y2(Y=C104, BF4; OPSR=phosphinooxide of the PSR ligand). A mixed-valence species cu″?(OPSEt)2Y2·Cu′(PSR)2Y has been isolated. The interaction of the PSR ligands with silver(I) and gold(III) salts has been also studied and gold(I) derivatives of the type [AuX(PSR)] have been isolated.
Complexes of copper and gold with phosphorus-sulfur bidentate ligands.
MORVILLO, ANTONINO
1986
Abstract
Copper(II) salts react with the bidentate hybrid ligands 1-thiophenyl-2-diphenylphosphinoethane (PSPh) and 1-thioethyl-2-diphehylphosphinoethane (PSEt) to yield copper(I) and/of copper(II) complexes of composition [Cu(PSR)2]Y andCu- (OPSR)2] Y2(Y=C104, BF4; OPSR=phosphinooxide of the PSR ligand). A mixed-valence species cu″?(OPSEt)2Y2·Cu′(PSR)2Y has been isolated. The interaction of the PSR ligands with silver(I) and gold(III) salts has been also studied and gold(I) derivatives of the type [AuX(PSR)] have been isolated.File in questo prodotto:
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