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EnglishHydroxylation or ketonization of alkanes is achieved using lithium or sodium hypochlorite in the presence of catalytic amounts of ruthenium(II) complexes in a biphasic dichloromethane-water system, at room temperature. The oxidation of cyclooctane is first order both in substrate and in catalyst: a kinetic isotope effect (k(H)/k(D)) = 5.6 was measured using cyclohexane-d12. A discussion is included concerning the origin of the different regioselectivities.
| Titolo: | HYPOCHLORITE-OXYFUNCTIONALIZATION OF SATURATED-HYDROCARBONS CATALYZED BY RUTHENIUM(II) COMPLEXES |
| Autori: | |
| Data di pubblicazione: | 1992 |
| Rivista: | |
| Abstract: | Hydroxylation or ketonization of alkanes is achieved using lithium or sodium hypochlorite in the presence of catalytic amounts of ruthenium(II) complexes in a biphasic dichloromethane-water system, at room temperature. The oxidation of cyclooctane is first order both in substrate and in catalyst: a kinetic isotope effect (k(H)/k(D)) = 5.6 was measured using cyclohexane-d12. A discussion is included concerning the origin of the different regioselectivities. |
| Handle: | http://hdl.handle.net/11577/139015 |
| Appare nelle tipologie: | 01.01 - Articolo in rivista |
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