The high yield synthesis of 3- and 4-(pentafluorosulfanyl)benzoic acid derivatives is described starting from the NO(2)-derivatives, which are reduced to the corresponding anilines. Then the NH(2)- group is converted to bromide and subsequently to the HC = O moiety. The benzaldeydes are then oxidised to the corresponding benzoic acids. The X-ray structure of 3-SF(5)-C(6)H(4)-COOH is also reported.
Synthesis and characterisation of 3-and 4-(pentafluorosulfanyl) benzoic acid derivatives X-ray structure of 3-SF(5)-C(6)H(4)-COOH
UGEL, ELISABETTA;BERTANI, ROBERTA;MILANI, ROBERTO;ZAGGIA, ALESSANDRO
2007
Abstract
The high yield synthesis of 3- and 4-(pentafluorosulfanyl)benzoic acid derivatives is described starting from the NO(2)-derivatives, which are reduced to the corresponding anilines. Then the NH(2)- group is converted to bromide and subsequently to the HC = O moiety. The benzaldeydes are then oxidised to the corresponding benzoic acids. The X-ray structure of 3-SF(5)-C(6)H(4)-COOH is also reported.
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