Tailored waste-based glasses as secondary raw materials for porcelain stoneware

The high temperature processing of porcelain stoneware products is attractive for the possibility to incorporate several inorganic wastes. However, even if recycling is an environmental benefit, it can be disadvantageous for the overall properties of the ceramic product, if the wastes are not selected in terms of their chemical and physical characteristics. In the present work several kind of industrial and urban wastes, such as mining residues, lime, glass from dismantled cathode ray tubes and soda-lime glass were used, after their vitrification. The newly formed glasses were used as partial substitution for natural feldspar sands (the glass content being from 5 to 7wt% of the total mix). Due to the specific (“tailored”) chemical formulation of the newly formed glasses, the modified products exhibited higher crystallization, with a more homogeneous microstructure, leading to significant improvements in reliability and indentation fracture toughness.