Hydrothermal treatment of 2,3-bis(20,600-bipyridyl)quinoxaline, molybdenum trioxide, cupric acetate and water unexpectedly forms the Cu(II) complex of a planar, macrocyclic 2-acyl-6,20-bipyridyl dimer, imbedded within a copper benzotrizolate-octamolybtate matrix. X-ray crystallographic characterization of this material, and scalar relativistic ZORA DFT modeling of the complex dication are presented.
Unusual Hydrothermal Synthesis of a Heteroaromatic Macrocyclic Complex
ORIAN, LAURA;
2008
Abstract
Hydrothermal treatment of 2,3-bis(20,600-bipyridyl)quinoxaline, molybdenum trioxide, cupric acetate and water unexpectedly forms the Cu(II) complex of a planar, macrocyclic 2-acyl-6,20-bipyridyl dimer, imbedded within a copper benzotrizolate-octamolybtate matrix. X-ray crystallographic characterization of this material, and scalar relativistic ZORA DFT modeling of the complex dication are presented.File in questo prodotto:
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