Enantiopure dendritic polyoxometalate frameworks were prepared by assembling chiral dendritic amines and acidic POM units. The solution CD, UV/Vis and vibrational CD investigations, and the efficiency of these hybrids in the asymmetric oxidation of thioanisole to sulfoxide (14 % ee), indicate significant induced optical activity in the POM cluster. Despite the modest ee, the present reaction confirms a chirality transfer to the POM unit.

Enantiopure Dendritic Polyoxometalates: Chirality Transfer from Dendritic Wedges to a POM Cluster for Asymmetric Sulfide Oxidation

CARRARO, MAURO;BONCHIO, MARCELLA;
2009

Abstract

Enantiopure dendritic polyoxometalate frameworks were prepared by assembling chiral dendritic amines and acidic POM units. The solution CD, UV/Vis and vibrational CD investigations, and the efficiency of these hybrids in the asymmetric oxidation of thioanisole to sulfoxide (14 % ee), indicate significant induced optical activity in the POM cluster. Despite the modest ee, the present reaction confirms a chirality transfer to the POM unit.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/2377032
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