A new catalytic aerobic oxidation of alcohols to aldehydes under green conditions was developed (room temperature and pressure, water solution, open vials). The water-soluble platinum(II) tetrasulfophthalocyanine (PtPcS) catalyst showed the best selectivity for carbonyl derivatives, and in particular for alpha,beta-unsaturated alcohols; the reactions are slow.
Catalytic aerobic oxidation of allylic alcohols to carbonyl compounds under mild conditions
MORVILLO, ANTONINO
2009
Abstract
A new catalytic aerobic oxidation of alcohols to aldehydes under green conditions was developed (room temperature and pressure, water solution, open vials). The water-soluble platinum(II) tetrasulfophthalocyanine (PtPcS) catalyst showed the best selectivity for carbonyl derivatives, and in particular for alpha,beta-unsaturated alcohols; the reactions are slow.
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