The title compounds form Diels–Alder cycloadducts with a number of dienes, which can be transformed into vic-bromo(trimethylstannyl)olefins, ultimate precursors for the synthesis of benzocyclotrimers via copper-mediated cyclotrimerization. The overall result is a formal condensation of three diatomic carbons with three dienes.

1-Bromo-2-(diphenylphosphinoyl)ethyne and 1-bromo-2-(p-tolylsulfinyl)ethyne: versatile reagents eventually leading to benzocyclotrimers

ZONTA, CRISTIANO;
2009

Abstract

The title compounds form Diels–Alder cycloadducts with a number of dienes, which can be transformed into vic-bromo(trimethylstannyl)olefins, ultimate precursors for the synthesis of benzocyclotrimers via copper-mediated cyclotrimerization. The overall result is a formal condensation of three diatomic carbons with three dienes.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/2381851
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