We report on the synthesis and EPR characterization of four new monoadducts of endohedral fullerenes encapsulating a nitrose atom (N@C60). The effect of different exohedral molecular structures fused to the fullerene cage is studied through the change of the fine structure parameters of the enclosed paramagnetic nitrogen atom in its quartet ground state
Synthesis and magnetic properties of N@C-60 derivatives
FRANCO, LORENZO;CORVAJA, CARLO;MAGGINI, MICHELE
2006
Abstract
We report on the synthesis and EPR characterization of four new monoadducts of endohedral fullerenes encapsulating a nitrose atom (N@C60). The effect of different exohedral molecular structures fused to the fullerene cage is studied through the change of the fine structure parameters of the enclosed paramagnetic nitrogen atom in its quartet ground state
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