Novel synthetic routes for the preparation of trinuclear copper(I) complexes with triscarbene ligands are presented, which yield higher purity products than the one previously described. The first crystal structure of one of these complexes is reported and confirms the expected structure. The trinuclear complexes proved to be efficient catalysts of Ullmann-type reactions as well as of the Sonogashira reaction.

Trinuclear copper(I) complexes with triscarbene ligands: catalysis of C-N and C-C coupling reactions

BIFFIS, ANDREA;TUBARO, CRISTINA;SCATTOLIN, ELENA;BASATO, MARINO;
2009

Abstract

Novel synthetic routes for the preparation of trinuclear copper(I) complexes with triscarbene ligands are presented, which yield higher purity products than the one previously described. The first crystal structure of one of these complexes is reported and confirms the expected structure. The trinuclear complexes proved to be efficient catalysts of Ullmann-type reactions as well as of the Sonogashira reaction.
2009
File in questo prodotto:
File Dimensione Formato  
111.pdf

accesso aperto

Tipologia: Published (publisher's version)
Licenza: Creative commons
Dimensione 340.71 kB
Formato Adobe PDF
340.71 kB Adobe PDF Visualizza/Apri
Pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/2434620
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 51
  • ???jsp.display-item.citation.isi??? 53
social impact