The Cp ring in [RuCl(Cp)(PPh3)(2)] undergoes an apparent nucleophilic attack by the carbanion carb (Hcarb = 2-Me-1,2-dicarba-closo-dodecaborane), to give an H-/carb(-) exchange process, which is favoured by coordination of the hydride to the ruthenium centre.

Nucleophilic substitution on a Ru-coordinated Cp ring by a carborane anion

BASATO, MARINO;BIFFIS, ANDREA;TUBARO, CRISTINA;
2004

Abstract

The Cp ring in [RuCl(Cp)(PPh3)(2)] undergoes an apparent nucleophilic attack by the carbanion carb (Hcarb = 2-Me-1,2-dicarba-closo-dodecaborane), to give an H-/carb(-) exchange process, which is favoured by coordination of the hydride to the ruthenium centre.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/2434952
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