A series of peptido[2]rotaxanes have been designed which contain a rigid helix as a significant part of their axle. One such rotaxane has been used to construct a reversible molecular device, in which, by virtue of the size of the inner cavity of the wheel relative to the outer diameter of the peptide helix, a rotation of the wheel might occur concomitantly with its translation along the axle.
Titolo: | A Rigid Helical Peptide Axle for a [2]Rotaxane Molecular Machine |
Autori: | |
Data di pubblicazione: | 2009 |
Rivista: | |
Abstract: | A series of peptido[2]rotaxanes have been designed which contain a rigid helix as a significant part of their axle. One such rotaxane has been used to construct a reversible molecular device, in which, by virtue of the size of the inner cavity of the wheel relative to the outer diameter of the peptide helix, a rotation of the wheel might occur concomitantly with its translation along the axle. |
Handle: | http://hdl.handle.net/11577/2435928 |
Appare nelle tipologie: | 01.01 - Articolo in rivista |
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