The mechanism of dissociative electron transfer (ET) to a series of organic chlorides has been investigated both at an inert electrode and at a catalytic surface such as Ag; electrocatalysis is important only when breaking of the carbon–halogen bond is concerted with the ET.
Relevance of electron transfer mechanism in electrocatalysis: the reduction of organic halides at silver electrodes
AHMED ISSE, ABDIRISAK;GENNARO, ARMANDO
2006
Abstract
The mechanism of dissociative electron transfer (ET) to a series of organic chlorides has been investigated both at an inert electrode and at a catalytic surface such as Ag; electrocatalysis is important only when breaking of the carbon–halogen bond is concerted with the ET.
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