2-nm gold nanoclusters coated with Zn(II) complexes bearing auxiliary hydrogen bond donors act as multivalent catalysts capable of promoting the hydrolysis of model phosphate diesters with exceptional activity and inducing DNA double strand cleavage.
Phosphate Diester and DNA Hydrolysis by a Multivalent, Nanoparticle-Based Catalyst
BONOMI, RENATO;SELVESTREL, FRANCESCO;SISSI, CLAUDIA;MANCIN, FABRIZIO;TONELLATO, UMBERTO;SCRIMIN, PAOLO MARIA
2008
Abstract
2-nm gold nanoclusters coated with Zn(II) complexes bearing auxiliary hydrogen bond donors act as multivalent catalysts capable of promoting the hydrolysis of model phosphate diesters with exceptional activity and inducing DNA double strand cleavage.
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