This paper provides an overview of the about 80 crystal structures of technetium complexes described in the past 5 years and exhibiting some peculiar structural features. In almost 90% of the compounds, technetium shows an odd oxidation number, and by a large majority the revised complexes are mononuclear and neutral. The review especially focuses on nitrido-Tc(V), oxo-Tc(V) and fac-[Tc(CO)(3)](+) complexes, which cover approximately one-half of the X-ray structural reports.
Structural overview of technetium compounds (2000-2004)
BANDOLI, GIULIANO;DOLMELLA, ALESSANDRO;AGOSTINI, STEFANIA
2006
Abstract
This paper provides an overview of the about 80 crystal structures of technetium complexes described in the past 5 years and exhibiting some peculiar structural features. In almost 90% of the compounds, technetium shows an odd oxidation number, and by a large majority the revised complexes are mononuclear and neutral. The review especially focuses on nitrido-Tc(V), oxo-Tc(V) and fac-[Tc(CO)(3)](+) complexes, which cover approximately one-half of the X-ray structural reports.
File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
CCR2006(4).pdf
Accesso riservato
Tipologia:
Published (Publisher's Version of Record)
Licenza:
Accesso privato - non pubblico
Dimensione
498.74 kB
Formato
Adobe PDF
|
498.74 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
