The photocurrent generation properties of a self-assembled monolayer formed by a helical hexapeptide carrying a pyrene group at the C-terminus and chemisorbed on a gold electrode through a lipoyl chain have been investigated by means of photoelectrochemical experiments. Anodic and cathodic photocurrents have been measured by simply changing the redox-active electrolyte in the electrochemical cell. (c) 2008 Elsevier Ltd. All rights reserved.
Photocurrent generation in peptide-based self-assembled monolayers on gold electrodes
TONIOLO, CLAUDIO;FORMAGGIO, FERNANDO;
2009
Abstract
The photocurrent generation properties of a self-assembled monolayer formed by a helical hexapeptide carrying a pyrene group at the C-terminus and chemisorbed on a gold electrode through a lipoyl chain have been investigated by means of photoelectrochemical experiments. Anodic and cathodic photocurrents have been measured by simply changing the redox-active electrolyte in the electrochemical cell. (c) 2008 Elsevier Ltd. All rights reserved.File in questo prodotto:
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