A novel hybrid N-heterocyclic carbene (NHC) palladium complex, integrating a totally inorganic and polyanionic decatungstate unit, has been synthesized following a convergent strategy. The interplay of the Pd binding domains with the inorganic scaffold is instrumental in accessing multi-turnover catalysis in C-C cross-coupling and aromatic dehalogenation reactions under MW-assisted protocols .
Polyoxometalate-Based N-Heterocyclic Carbene (NHC) Complexes for Palladium-Mediated C-C Coupling and Chloroaryl Dehalogenation Catalysis
BERARDI, SERENA;CARRARO, MAURO;SARTOREL, ANDREA;SCORRANO, GIANFRANCO;BONCHIO, MARCELLA
2010
Abstract
A novel hybrid N-heterocyclic carbene (NHC) palladium complex, integrating a totally inorganic and polyanionic decatungstate unit, has been synthesized following a convergent strategy. The interplay of the Pd binding domains with the inorganic scaffold is instrumental in accessing multi-turnover catalysis in C-C cross-coupling and aromatic dehalogenation reactions under MW-assisted protocols .File in questo prodotto:
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