An improved synthesis of platinum acetate is reported in detail. This tetrameric complex reacts with PPh3 or P-n-Bu3 at room temperature to give the thermodynamically unstable bis-substituted trans -[Pt(OAc)2L2] complexes, which are not easily accessible via other routes. The structure of the new compound trans-[Pt(OAc)2(PPh3)2] has been determined by X-ray analysis.

Reaction of platinum acetate with phosphines and molecular structure of trans-[Pt(OAc)(2)(PPh3)(2)]

BASATO, MARINO;BIFFIS, ANDREA;MARTINATI, GIANLUCA;TUBARO, CRISTINA;
2003

Abstract

An improved synthesis of platinum acetate is reported in detail. This tetrameric complex reacts with PPh3 or P-n-Bu3 at room temperature to give the thermodynamically unstable bis-substituted trans -[Pt(OAc)2L2] complexes, which are not easily accessible via other routes. The structure of the new compound trans-[Pt(OAc)2(PPh3)2] has been determined by X-ray analysis.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/2461617
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