The μ-carbido dimer [(PcFe)2C] and its derivatives of formula [{(L)PcFe}2C] (L = acetone, pyridine, 4-methylpyridine, 1-methylimidazole, piperidine) have been prepared and studied by IR, Mössbauer, EPR, and NMR spectroscopy and magnetic susceptibility determinations. All of the complexes appear to contain Fe(IV). © 1989, American Chemical Society. All rights reserved.
High-valent Iron Phthalocyanine Five- and Six-coordinated μ-Carbido Dimers
RUSSO, UMBERTO;ZANONATO, PIER LUIGI
1989
Abstract
The μ-carbido dimer [(PcFe)2C] and its derivatives of formula [{(L)PcFe}2C] (L = acetone, pyridine, 4-methylpyridine, 1-methylimidazole, piperidine) have been prepared and studied by IR, Mössbauer, EPR, and NMR spectroscopy and magnetic susceptibility determinations. All of the complexes appear to contain Fe(IV). © 1989, American Chemical Society. All rights reserved.File in questo prodotto:
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