The reaction of trans-[PtCl2(NCMe)2] with a 5-fold excess of MeNH2 in CH2Cl2 at −10°C affords in high yield the bis-amidine complex trans-[PtCl2{Z-N(H)C(NHMe)Me}2] (1), where both the amidine ligands assume the Z configuration corresponding to the trans addition of the amine along the CN triple bond. Compound 1 has been fully characterized by spectroscopic techniques and also by X-ray diffraction analysis.
Reactions of platinum(II)-nitrile complexes with amines. Synthesis and X-ray structure of the platinum(II)-amidine complex trans-[PtCl2{Z-N(H)=C(NHMe)Me}2]
BERTANI, ROBERTA;MICHELIN, RINO;MOZZON, MIRTO;BANDOLI, GIULIANO;DOLMELLA, ALESSANDRO
2000
Abstract
The reaction of trans-[PtCl2(NCMe)2] with a 5-fold excess of MeNH2 in CH2Cl2 at −10°C affords in high yield the bis-amidine complex trans-[PtCl2{Z-N(H)C(NHMe)Me}2] (1), where both the amidine ligands assume the Z configuration corresponding to the trans addition of the amine along the CN triple bond. Compound 1 has been fully characterized by spectroscopic techniques and also by X-ray diffraction analysis.File in questo prodotto:
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