The asymmetric epoxidation of terminal alkenes with hydrogen peroxide can occur catalyzed by perfluorophenyl platinum(II) complexes. For the investigated dienes, the epoxidation occurred selectively at the terminal double bond with complete regioselectivity.
Asymmetric Epoxidation of Terminal Alkenes with Hydrogen Peroxide Catalyzed by Pentafluorophenyl Pt(II) Complexes
SGARBOSSA, PAOLO;MICHELIN, RINO;
2006
Abstract
The asymmetric epoxidation of terminal alkenes with hydrogen peroxide can occur catalyzed by perfluorophenyl platinum(II) complexes. For the investigated dienes, the epoxidation occurred selectively at the terminal double bond with complete regioselectivity.
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