we report a direct observation, by electrospray ionization mass spectrometry, of the intermediate [VO(OH2)(OH)- (OBr)]+, which may be involved in the catalytic cycle of the V-HalPO enzymes. Ab initio calculations also support the stability of such a species.

Vanadium-bromoperoxidase-mimicking systems: Direct evidence of a hypobromite-like vanadium intermediate

CARRARO, MAURO;MORO, STEFANO
2003

Abstract

we report a direct observation, by electrospray ionization mass spectrometry, of the intermediate [VO(OH2)(OH)- (OBr)]+, which may be involved in the catalytic cycle of the V-HalPO enzymes. Ab initio calculations also support the stability of such a species.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/2473660
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