we report a direct observation, by electrospray ionization mass spectrometry, of the intermediate [VO(OH2)(OH)- (OBr)]+, which may be involved in the catalytic cycle of the V-HalPO enzymes. Ab initio calculations also support the stability of such a species.
Vanadium-bromoperoxidase-mimicking systems: Direct evidence of a hypobromite-like vanadium intermediate
CARRARO, MAURO;MORO, STEFANO
2003
Abstract
we report a direct observation, by electrospray ionization mass spectrometry, of the intermediate [VO(OH2)(OH)- (OBr)]+, which may be involved in the catalytic cycle of the V-HalPO enzymes. Ab initio calculations also support the stability of such a species.File in questo prodotto:
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