The reaction between Me S-prolinate and meso-norbornene derived anhydrides was found to give amido-acids with excellent asym. induction. This methodol. provides an inexpensive route for the prepn. of optically pure, polycyclic, highly functionalized starting materials for natural and unnatural product synthesis on a large scale.
Asymmetric Desymmetrisation of Meso-Norbornene Anhydrides Utilising Methyl Prolinate as a Chiral Reagent
ZAGOTTO, GIUSEPPE
1995
Abstract
The reaction between Me S-prolinate and meso-norbornene derived anhydrides was found to give amido-acids with excellent asym. induction. This methodol. provides an inexpensive route for the prepn. of optically pure, polycyclic, highly functionalized starting materials for natural and unnatural product synthesis on a large scale.File in questo prodotto:
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