In Paper I we proved the profile invariance of the first permitted electronic transition of the typical Polycyclic Aromatic Hydrocarbon cation C32H14+ as a first necessary check for the ``strong'' PAHs hypothesis. In this paper we derive a quantitative relation between the intensities of the former band, which ought to be observable in absorption in the visible range, and those of the far-IR bands, which are predicted by the PAH model to be simultaneously present in emission. Contrary to the mid-IR bands, collectively known as ``Unidentified Infrared Bands'' (UIBs), which do not discriminate specific molecules, the far IR, skeletal bands can be expected to be a fingerprint of each single species. This fact provides a number of independent constraints which must be simultaneously fulfilled for a successful PAH identification. Our approach thus offers a powerful criterion for the identification of specific PAHs, both in the presently available ISO data and in those of the forthcoming SIRTF and Herschel missions. As an interesting by-product, we quantitatively evaluate the impact of isotopic substitutions (13C->12C and D -> H) on the resulting infrared emission bands.

Testing the "strong" PAHs hypothesis. II. A quantitative link between DIBs and far-IR emission features

BENVENUTI, PIERO
2003

Abstract

In Paper I we proved the profile invariance of the first permitted electronic transition of the typical Polycyclic Aromatic Hydrocarbon cation C32H14+ as a first necessary check for the ``strong'' PAHs hypothesis. In this paper we derive a quantitative relation between the intensities of the former band, which ought to be observable in absorption in the visible range, and those of the far-IR bands, which are predicted by the PAH model to be simultaneously present in emission. Contrary to the mid-IR bands, collectively known as ``Unidentified Infrared Bands'' (UIBs), which do not discriminate specific molecules, the far IR, skeletal bands can be expected to be a fingerprint of each single species. This fact provides a number of independent constraints which must be simultaneously fulfilled for a successful PAH identification. Our approach thus offers a powerful criterion for the identification of specific PAHs, both in the presently available ISO data and in those of the forthcoming SIRTF and Herschel missions. As an interesting by-product, we quantitatively evaluate the impact of isotopic substitutions (13C->12C and D -> H) on the resulting infrared emission bands.
2003
Inglese
410
639
648
10
Internazionale
The Space Science category includes resources dealing with all areas of astronomy and astrophysics, which are concerned with celestial bodies and the observation and interpretation of radiation received in the vicinity of the Earth from the component parts of the universe. These resources deal with the physical properties of celestial bodies, such as luminosity, size, mass, density, temperature, chemical composition and their origin and evolution. Planetary science may also be included in this CC category.
none
G., Mulas; G., Malloci; Benvenuti, Piero
01 CONTRIBUTO IN RIVISTA::01.01 - Articolo in rivista
info:eu-repo/semantics/article
3
262
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/2488134
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