The title compound C25H21FSn crystallizes in the orthorhombic system, space group Pbca, with a = 20.172 (2) Angstrom, b = 26.732 (2) Angstrom, c = 7.766 (1) Angstrom, Z = 8. The molecular structure shows an almost undistorted tetrahedral coordination about Sn and a propeller-like conformation of the SnPh(3) group, the conformation of the para-substituted benzyl moiety is strongly controlled by the configuration of the SnPh(3) group. Physical properties of C25H21FSn are explained in terms of structural data. The crystal structure has been refined to R = 0.024 for 2435 observed reflections
The crystal structure of p-fluorobenzyltriphenyltin(IV)
MARTON, DANIELE;STIVANELLO, DIEGO;
1996
Abstract
The title compound C25H21FSn crystallizes in the orthorhombic system, space group Pbca, with a = 20.172 (2) Angstrom, b = 26.732 (2) Angstrom, c = 7.766 (1) Angstrom, Z = 8. The molecular structure shows an almost undistorted tetrahedral coordination about Sn and a propeller-like conformation of the SnPh(3) group, the conformation of the para-substituted benzyl moiety is strongly controlled by the configuration of the SnPh(3) group. Physical properties of C25H21FSn are explained in terms of structural data. The crystal structure has been refined to R = 0.024 for 2435 observed reflectionsFile in questo prodotto:
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