Models of motion continuously varying from random jumps to rotational diffusion have been tested to simulate the ESR lineshape of biradical metal chelates spin probes in the slow-motion region. The evidence of a diffusional regime for the molecular reorientation contrasts with the anomalous temperature dependence of the process. © 1980.
Rotational motions of biradical metal chelates in polar solvents
MORO, GIORGIO;NORDIO, PIER LUIGI;
1980
Abstract
Models of motion continuously varying from random jumps to rotational diffusion have been tested to simulate the ESR lineshape of biradical metal chelates spin probes in the slow-motion region. The evidence of a diffusional regime for the molecular reorientation contrasts with the anomalous temperature dependence of the process. © 1980.
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