Gas-liquid chromatography, thin-layer chromatography and 13C NMR spectrometry have been employed to identify and analyse diastereomeric mixtures of the β-methylalcohols RCH(OH)-CH(CH3)-CHCH2 where R = CH3, C2H5, n-C3H7, n-C4H9, n-C5H11, iso-C3H7, sec.-C4H9, tert.-C4H9. The existence of a relationship between the analytical data and diastereomeric configuration of the alcohols is pointed out for all the three methods adopted
GAS-LIQUID-CHROMATOGRAPHY, THIN-LAYER CHROMATOGRAPHY AND C-13 NUCLEAR-MAGNETIC-RESONANCE SPECTROMETRY IN THE ANALYSIS OF DIASTEREOMERIC MIXTURES OF R-CH(OH)-CH(CH3)-CH=CH2 ALCOHOLS
FURLANI, DONATELLA;MARTON, DANIELE
1986
Abstract
Gas-liquid chromatography, thin-layer chromatography and 13C NMR spectrometry have been employed to identify and analyse diastereomeric mixtures of the β-methylalcohols RCH(OH)-CH(CH3)-CHCH2 where R = CH3, C2H5, n-C3H7, n-C4H9, n-C5H11, iso-C3H7, sec.-C4H9, tert.-C4H9. The existence of a relationship between the analytical data and diastereomeric configuration of the alcohols is pointed out for all the three methods adopted
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