Cu(II) and a bis-beta-diketone ligand generate a small constitutional dynamic library (CDL). The designed introduction of a well suited guest drives the self-sorting of the system toward a supramolecular triangle. Alternatively, the triangle self-assembly is templated by the same guest in a one-pot synthesis.
A templating guest sorts out a molecular triangle from a dimer–trimer constitutional dynamic library
RANCAN, MARZIO;DOLMELLA, ALESSANDRO;ARMELAO, LIDIA
2012
Abstract
Cu(II) and a bis-beta-diketone ligand generate a small constitutional dynamic library (CDL). The designed introduction of a well suited guest drives the self-sorting of the system toward a supramolecular triangle. Alternatively, the triangle self-assembly is templated by the same guest in a one-pot synthesis.
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