The structure of the title compound, trichloro-2 kappa(3)Cl-(5,10,15,20-tetraphenylporphyrinato- 1 kappa(4)N(21,22,)(23,24))rhodium(III)tin(II)(Rh-Sn), [RhSnCl3(C44H28N4)], consists of well separated units in which the Rh atom is five-coordinate at the center of a square-pyramidal polyhedron with the Sn atom at the top. The macrocylic unit is planar with the Rh atom displaced by only 0.02 Angstrom from the ring plane. The Rh-Sn bond length is 2.450 (1) Angstrom.
Trichlorotin(II)–(meso-Tetraphenylporphyrinato)rhodium(III), a Porphyrin Derivative with an Rh—Sn Bond
BANDOLI, GIULIANO;DOLMELLA, ALESSANDRO
1995
Abstract
The structure of the title compound, trichloro-2 kappa(3)Cl-(5,10,15,20-tetraphenylporphyrinato- 1 kappa(4)N(21,22,)(23,24))rhodium(III)tin(II)(Rh-Sn), [RhSnCl3(C44H28N4)], consists of well separated units in which the Rh atom is five-coordinate at the center of a square-pyramidal polyhedron with the Sn atom at the top. The macrocylic unit is planar with the Rh atom displaced by only 0.02 Angstrom from the ring plane. The Rh-Sn bond length is 2.450 (1) Angstrom.File in questo prodotto:
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