Aziridine is observed to react spontaneously in THF at room temperature or below with the coordinated RNC ligand in each of the neutral isocyanide complexes cis-Cl2(L)M(CNR) (M = Pd, R = t-Bu, p-MeOC6H4, L = PPh3, PMe2Ph; M = Pt, R = p-MeOC6H4, p-MeC6H4, L = PPh3) to form the corresponding five-membered cyclic diaminocarbene complexes cis-Cl2(L)M [CN(R)CH2CH2NH].
Reactions of Aziridine, Thiirane, and Oxirane With Isocyanide Ligands In Complexes of Palladium(II) and Platinum(II) - Syntheses of Neutral 5-membered Cyclic Diaminocarbene, Aminothiocarbene and Aminooxycarbene Compounds
BERTANI, ROBERTA;MOZZON, MIRTO;MICHELIN, RINO
1988
Abstract
Aziridine is observed to react spontaneously in THF at room temperature or below with the coordinated RNC ligand in each of the neutral isocyanide complexes cis-Cl2(L)M(CNR) (M = Pd, R = t-Bu, p-MeOC6H4, L = PPh3, PMe2Ph; M = Pt, R = p-MeOC6H4, p-MeC6H4, L = PPh3) to form the corresponding five-membered cyclic diaminocarbene complexes cis-Cl2(L)M [CN(R)CH2CH2NH].File in questo prodotto:
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