Electrophilic isocyanide ligands in cationic Pt(II) and Pd(II) complexes of the type trans-[L2M(CNR)X]BF4 (I) (L = phosphine; R = alkyl, aryl; X = halide, Me) are converted to the five-membered cyclic diaminocarbene derivatives trans-(L2M[CN(R)CH2CH2N(H)]X)BF4 (II) by reaction with 2-bromoethylamine hydrobromide in the presence of n-BuLi.
Transition-metal-promoted Cyclization Reactions of Isocyanide Ligands - Synthesis of Cyclic Aminooxycarbene Complexes of Platinum(II) and X-ray Structure of Trans-((PPh3)2Pt[CN(C6H4-p-Me)CH2CH2O]Br)BF4
MICHELIN, RINO;
1988
Abstract
Electrophilic isocyanide ligands in cationic Pt(II) and Pd(II) complexes of the type trans-[L2M(CNR)X]BF4 (I) (L = phosphine; R = alkyl, aryl; X = halide, Me) are converted to the five-membered cyclic diaminocarbene derivatives trans-(L2M[CN(R)CH2CH2N(H)]X)BF4 (II) by reaction with 2-bromoethylamine hydrobromide in the presence of n-BuLi.File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
